高浓度CO2下添加甲苯对正庚烷着火特性的影响

张跃威,姚圣卓,刘永峰,刘海峰,宋金瓯

车用发动机 ›› 2022, Vol. 0 ›› Issue (4) : 8-16.

车用发动机 ›› 2022, Vol. 0 ›› Issue (4) : 8-16.
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高浓度CO2下添加甲苯对正庚烷着火特性的影响

  • 张跃威1,姚圣卓1,刘永峰1,刘海峰2,宋金瓯2
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Effect of Toluene Addition on Ignition Characteristics of N-Heptane under High CO2 Concentration

  • ZHANG Yuewei1,YAO Shengzhuo1,LIU Yongfeng1,LIU Haifeng2,SONG Jin′ou2
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摘要

为了对柴油在CO2-O2环境下的着火特性进行研究,建立了以70%正庚烷30%甲苯混合物作为柴油表征燃料的着火延迟时间模型。该模型考虑了高浓度CO2对着火的阻燃效应,运用多元线性回归分析方法,得到了着火延迟时间与温度、密度以及浓度等之间的函数关系。结合正庚烷甲苯耦合机理的仿真和可视化定容燃烧弹试验,对着火延迟时间模型进行了验证,并深入研究了不同工况下影响着火特性的重要因素。结果表明:该模型能较好地预测柴油在CO2-O2氛围下的着火延迟时间,且在50%CO2环境下的平均误差为5.71%; CO2的热效应对着火延迟时间的影响起主导作用,而当CO2体积分数大于60%时,CO2的第三体碰撞效应对着火发生的促进作用显著增强,另外,CO2浓度变化对OH自由基产率的影响很大。

Abstract

In order to research the ignition characteristics of diesel in CO2-O2 environment, an ignition delay time model was established using mixture of 70% nheptane and 30% toluene as diesel fuel. The model took into account the flame retardant effect of high CO2 concentration on ignition and obtained the functional relationship of ignition delay time with temperature, density and concentration by using multiple linear regression analysis method. The ignition delay time model was verified by combining the simulation of nheptane/toluene coupling mechanism and the test of visual constant volume combustion bomb, and the important factors affecting the ignition characteristics under different working conditions were investigated. The results show that the model can well predict the diesel ignition delay time in CO2-O2 environment, and the average error is 5.71% in 50%CO2environment. The thermal effect of CO2 plays a dominant role in the impact on ignition delay time and the thirdbody collision effect of CO2 promtes significantly the ignition when the CO2volume fraction is greater than 60%. In addition, the CO2 concentration variation has a significant effect on the rate of OH radical production.

关键词

正庚烷 / 甲苯 / 定容燃烧弹 / 着火特性

Key words

n-heptane / toluene / constant volume combustion bomb / ignition characteristics

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导出引用
张跃威,姚圣卓,刘永峰,刘海峰,宋金瓯. 高浓度CO2下添加甲苯对正庚烷着火特性的影响[J]. 车用发动机. 2022, 0(4): 8-16
ZHANG Yuewei,YAO Shengzhuo,LIU Yongfeng,LIU Haifeng,SONG Jin′ou. Effect of Toluene Addition on Ignition Characteristics of N-Heptane under High CO2 Concentration[J]. Vehicle Engine. 2022, 0(4): 8-16

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