应对国六排放的柴油机尾气NOx催化转化剂的试制研究

韦夏夏,谭宗勇,陈梦寅,刘来君,唐富顺,孙强,刘光文

车用发动机 ›› 2021, Vol. 0 ›› Issue (1) : 69.

车用发动机 ›› 2021, Vol. 0 ›› Issue (1) : 69. DOI: 10.3969/j.issn.1001-2222.2021.01.012
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应对国六排放的柴油机尾气NOx催化转化剂的试制研究

  • 韦夏夏1,谭宗勇1,陈梦寅1,刘来君1,唐富顺1,孙强2,刘光文2
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Preparation of NOx Converting Catalysts for Diesel Engine Exhaust to Meet China Ⅵ Emission Limit Requirement

  • WEI Xiaxia1,TAN Zongyong1,CHEN Mengyin1,LIU Laijun1,TANG Fushun1,SUN Qiang2,LIU Guangwen2
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摘要

研究了活性组分负载方式对V2O5-WO3/TiO2催化剂SCR性能的影响,通过调变助剂组分改善其低温窗口特性,并在稳态工况条件下考察了制备的蜂窝催化剂样品低温SCR催化性能。结果表明,活性组分的负载方式对V2O5-WO3/TiO2催化剂SCR性能影响较大,共浸法制备的V2O5-WO3/TiO2催化剂,WOx物种和VOx物种在载体表面分散均匀,具有较优的SCR活性,同时通过CeO2和SnO2组分的调变,其低温SCR性能显著改善。稳态工况试验表明,共浸渍法制备的CeO2、SnO2调变型V2O5-WO3/TiO2蜂窝催化剂样品具有稳定优异的低温SCR催化性能,具有潜在的满足国六排放柴油发动机尾气NOx转化的商业价值。

Abstract

The effects of loading methods of active components on the SCR performance of V2O5-WO3/TiO2 catalyst were studied, the low-temperature window characteristics of catalyst improved by changing the assistant components, and the catalytic performance of prepared honeycomb catalyst sample was investigated under steadystate conditions. The results showed that the loading methods of active components had great influence on the SCR performance of V2O5-WO3/TiO2 catalyst. WOx species and VOx species were evenly dispersed on the surface of TiO2 carrier with better SCR activity for the V2O5-WO3/TiO2 catalyst prepared by co-impregnation method. Meanwhile, the low temperature SCR performance significantly improved through the modulation of CeO2 and SnO2 components. The steady-state condition test results showed that the CeO2 and SnO2 modified V2O5-WO3/TiO2 honeycomb catalyst samples prepared by co-impregnation method had stable and excellent SCR performance at low temperature and had potential commercial value for the NOx conversion of diesel engine exhaust which meet China Ⅵ emission limit requirement.

关键词

柴油机 / 选择性催化还原 / 催化剂 / 制备

Key words

diesel engine / selective catalytic reduction(SCR) / catalyst / preparation

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导出引用
韦夏夏,谭宗勇,陈梦寅,刘来君,唐富顺,孙强,刘光文. 应对国六排放的柴油机尾气NOx催化转化剂的试制研究[J]. 车用发动机. 2021, 0(1): 69 https://doi.org/10.3969/j.issn.1001-2222.2021.01.012
WEI Xiaxia,TAN Zongyong,CHEN Mengyin,LIU Laijun,TANG Fushun,SUN Qiang,LIU Guangwen. Preparation of NOx Converting Catalysts for Diesel Engine Exhaust to Meet China Ⅵ Emission Limit Requirement[J]. Vehicle Engine. 2021, 0(1): 69 https://doi.org/10.3969/j.issn.1001-2222.2021.01.012

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